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Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2324
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dc.contributor.authorUsha, K.-
dc.contributor.authorSadashiva, B.K.-
dc.contributor.authorVijayan, Kalyani-
dc.date.accessioned2007-05-17T10:15:10Z-
dc.date.available2007-05-17T10:15:10Z-
dc.date.issued1994-02-
dc.identifier.citationMolecular Crystals and Liquid Crystals, 1994, Vol.241 , p91-102en
dc.identifier.issn1058-725X-
dc.identifier.urihttp://hdl.handle.net/2289/2324-
dc.descriptionRestricted Access.en
dc.description.abstractCrystal structures of the transition metal complexes bis[1,3-di(p-n-octylphenyl)propane-1,3-dionato palladium(II) and bis[11,3-di(p-n-octylphenyl)propane-1,3-dionato nickel(II) have been solved and refined to R = 0.051 and 0.064 respectively, using diffractometer collected X-ray data. The palladium and the nickel complexes are found to be isomorphous with the P-form of the copper complex bis[1,3- di(p-n-octylphenyl propane-1,3-dionato copper(II). Despite the unambiguous structural isomorphism, only the palladium and the copper complexes are mesogenic; the nickel complex is reportedly non- mesogenic. In the crystal structures, the metal atoms are surrounded by four oxygen atoms in a square planar arrangement. The octyl chains are fully extended in an all-trans conformation. The crystal structures are characterized by both layer-like and columnar arrangement of molecules.en
dc.format.extent505744 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.publisherGordon and Breach Science Publishers.en
dc.relation.urihttp://dx.doi.org/10.1080/10587259408029747en
dc.rights1994 OPA (Overseas Publishers Association) N.V.en
dc.subjectdiscoticen
dc.subjectcrystal structureen
dc.subjectisomorphousen
dc.subjectNi complexen
dc.subjectPd complexen
dc.titleCrystal and molecular structures of isomorphous bis[1,3-di(p-n- octylphenyl)propane-1,3-dionato palladium(II) and bis[1,3-di(p-n-octylphenyl)propane-1,3-dionato] nickel(II)en
dc.typeArticleen
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