Crystal and molecular structure of the discogen bis[1,3-di(p-n-decylphenyl)propane-1,3-dionato]palladium(II)

Usha, K.; Vijayan, Kalyani; Sadashiva, B.K.; Rao, P.R.

Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2337

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DC Field	Value	Language
dc.contributor.author	Usha, K.	-
dc.contributor.author	Vijayan, Kalyani	-
dc.contributor.author	Sadashiva, B.K.	-
dc.contributor.author	Rao, P.R.	-
dc.date.accessioned	2007-05-19T06:53:21Z	-
dc.date.available	2007-05-19T06:53:21Z	-
dc.date.issued	1990-08	-
dc.identifier.citation	Molecular Crystals and Liquid Crystals, 1990, Vol.185 , p1-11	en
dc.identifier.issn	1058-725X	-
dc.identifier.uri	http://hdl.handle.net/2289/2337	-
dc.description	Restricted Access.	en
dc.description.abstract	The transition metal containing discogen, bis[1,3-di(p-n-decylphenyl)propane-1,3-dionato]palladium(II) crystallizes in the triclinic space group P1 with one molecule in a unit cell of dimensions a = 10.260(2), b = 12.961(2), c = 13.403(2)Å, agr = 110.54(1), b.beta = 101.75(1) and b.gamma = 98.44(1)°. The crystal structure was solved by direct methods and refined using full matrix least squares procedure. The palladium atom is lying on an inversion center. The decyl chains are fully extended in an all trans conformation. In the crystal structure, the molecules form a tilted columnar arrangement. The angle between the normal to the core and the column axis is 68°. Each column is surrounded by six others. Along the column axis, adjacent palladium atoms are separated by 10.26Å.	en
dc.format.extent	424900 bytes	-
dc.format.mimetype	application/pdf	-
dc.language.iso	en	en
dc.publisher	Gordon and Breach Science Publishers.	en
dc.relation.uri	http://dx.doi.org/10.1080/00268949008038485	en
dc.rights	1990 OPA (Overseas Publishers Association) N.V.	en
dc.title	Crystal and molecular structure of the discogen bis[1,3-di(p-n-decylphenyl)propane-1,3-dionato]palladium(II)	en
dc.type	Article	en
Appears in Collections:	Research Papers (SCM)

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