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Title: | Mesomorphic properties of a homologous series of aryl beta-diketones and a few related derivatives |
Authors: | Sadashiva, B.K. Rani Rao, P. Srikanta, B.S. |
Keywords: | b.beta-diketone smectic A phase isomerism substituent effect |
Issue Date: | Mar-1989 |
Publisher: | Gordon and Breach Science Publishers. |
Citation: | Molecular Crystals and Liquid Crystals, 1989, Vol.168, p103-109 |
Abstract: | A new homologous series of nine [l-(p-n-alkylbiphenyl)3-(phenyl)propane]1,3-diones have been prepared and their mesomorphic properties studied. The first four homologues in the series exhibit the classical nematic phase and a smectic phase, the next five showing only a smectic phase. The optical textures, miscibility and the X-ray data establish that the smectic phase is of the A1 type. This is perhaps the first instance of a b.beta-diketone exhibiting a nematic as well as a smectic A1 phase. In addition, a few similar isomeric b.beta-diketones have also been synthesized to study the terminal substituent effect on the mesomorphic properties. |
Description: | Restricted Access. |
URI: | http://hdl.handle.net/2289/2348 |
ISSN: | 1058-725X |
Alternative Location: | http://dx.doi.org/10.1080/00268948908045963 |
Copyright: | 1989 OPA (Overseas Publishers Association) N.V. |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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1989 MCLC V168 p103.pdf Restricted Access | Restricted Access | 249.81 kB | Adobe PDF | View/Open Request a copy |
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