Please use this identifier to cite or link to this item:
http://hdl.handle.net/2289/2859
Title: | Highly aligned lamellar lipid domains induced by macroscopic confinement |
Authors: | Nieh, M.P. Raghunathan, V.A. Wang, H. Katsaras, J. |
Issue Date: | 2003 |
Publisher: | American Chemical Society |
Citation: | Langmuir; (Research Article); 2003; 19(17); 6936-6941 |
Abstract: | We have carried out neutron diffraction experiments on a lipid mixture in a macroscopically confined sample geometry (1 mm gap) and have observed the transformation of bilayered micelles into two distinct orientationally aligned domains of perforated lamellae seemingly littered with defects. Depending on the separation of the confining surfaces, the defects can lie on a two-dimensional centered rectangular lattice where the angle, , between lamellar domains can vary. The particular lamellar phase is shown to be metastable and eventually relaxes, either in time or by perturbation of the sample by centrifugation, into aligned multibilayer stacks of single orientation. |
Description: | Restricted Access. |
URI: | http://hdl.handle.net/2289/2859 |
ISSN: | 0743-7463 1520-5827 (Online) |
Alternative Location: | http://dx.doi.org/10.1021/la034549y |
Copyright: | 2003 American Chemical Society |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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2003 Langmuir V19 p6936.pdf Restricted Access | Restricted Access | 527.85 kB | Adobe PDF | View/Open Request a copy |
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