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http://hdl.handle.net/2289/3177
Title: | The conformation of (μ-butatriene)hexacarbonyldiiron complex from proton NMR studies in three nematic phases |
Authors: | Arumugam, S. Kunwar, A.C. Khetrapal, C.L. |
Issue Date: | Apr-1984 |
Publisher: | Elsevier B.V. |
Citation: | Journal of Organometallic Chemistry, 1984, Vol.265, p73-76 |
Abstract: | Proton NMR spectroscopy in three different liquid crystals has been used to determine two conformational angles of (μ-butatriene)hexacarbonyldiiron complex, namely the angle between the two CH2 planes and the dihedral angle between the two planes containing four carbon atoms of the butatriene moiety. The values are 44 and 46°, respectively. The direct and the indirect geminal HH couplings are shown to be of the same sign in the liquid crystals with positive diamagnetic anisotropy. |
Description: | Restricted Access. |
URI: | http://hdl.handle.net/2289/3177 |
ISSN: | 0022-328X |
Alternative Location: | http://dx.doi.org/10.1016/0022-328X(84)80053-4 |
Copyright: | 1984 Elsevier B.V. |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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1984 JOMC V265 p73.pdf Restricted Access | Restricted Access | 209.35 kB | Adobe PDF | View/Open Request a copy |
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