Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands

Rudresha, B.J.; Bhat, Ramachandra B.; Sampath Kumar, H.C.; Shiva Kumar, K.I.; Safakath, K.; Philip, Reji

Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/4286

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DC Field	Value	Language
dc.contributor.author	Rudresha, B.J.	-
dc.contributor.author	Bhat, Ramachandra B.	-
dc.contributor.author	Sampath Kumar, H.C.	-
dc.contributor.author	Shiva Kumar, K.I.	-
dc.contributor.author	Safakath, K.	-
dc.contributor.author	Philip, Reji	-
dc.date.accessioned	2012-01-19T11:24:06Z	-
dc.date.available	2012-01-19T11:24:06Z	-
dc.date.issued	2011-03	-
dc.identifier.citation	Synthetic Metals, 2011, Vol.161, p535	en
dc.identifier.issn	0379-6779	-
dc.identifier.uri	http://hdl.handle.net/2289/4286	-
dc.description	Restricted Access.	en
dc.description.abstract	This research article describes the synthesis, characterization and third-order nonlinear optical studies of copper(I) complexes [Cu(Br)(N,N'-C(12)H(6)N(2)O(2))(PPh(3))] and [Cu(I)(N,N'-C(12)H(6)N(2)O(2))(PPh(3))] abbreviated as [CuBrLPPh(3)] (1) and [CulLPPh(3)] (2) (L= 1,10-phenanthroline-5,6-dione). Nonlinear optical properties of the complexes are investigated at 532 nm using single beam Z-scan and degenerate four-wave mixing (DFWM) techniques employing nanosecond laser pulses. The complexes show optical limiting behaviour due to "effective" two-photon absorption. The values of the effective two-photon absorption (2PA) coefficients (beta), third-order nonlinear susceptibilities (chi((3))), and figures of merit (F), are calculated	en
dc.language.iso	en	en
dc.publisher	Elsevier B.V.	en
dc.relation.uri	http://dx.doi.org/10.1016/j.synthmet.2010.12.006	en
dc.rights	2010 Elsevier B.V.	en
dc.subject	Copper complexes	en
dc.subject	1,10-Phenanthroline-5,6-dione	en
dc.subject	LMCT	en
dc.subject	Two-photon absorption	en
dc.subject	Z-scan	en
dc.subject	Degenerate four wave mixing	en
dc.title	Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands	en
dc.type	Article	en
Appears in Collections:	Research Papers (LAMP)

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