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http://hdl.handle.net/2289/6413| Title: | Liquid/Single crystal structure analysis: Synthesis and characterization of a Trimethylsilyl derived rod shaped Mesogen. |
| Authors: | Srinivasa, H.T. Palakshamurthy, B.S. Velmurugan, D. Devarajegowda, H.C. Hariprasad, S. |
| Issue Date: | Dec-2015 |
| Publisher: | Slovenian Chemical Society |
| Citation: | Acta Chimica Slovenica , 2015, Vol. 62, p 768-774 |
| Abstract: | The synthesis 4-[4'-cyanophenoxy-carbonyl-phenyl-4-(trimethylsilyl)ethynyl]benzoate a rod shaped liquid crystal of Smectic phase is reported. The single-crystal diffraction studies indicate triclinic crystal system in the space group with unit cell parameters a = 5.9577(2) Å, b = 8.0398(3) Å, c = 25.8842(9) Å, α = 86.096(2), β = 89.912(2), γ =2.919(2), Z = 2, and V = 1182.16(7). The crystal structure is stabilized by C–H· · ·O intra-molecular interactions. The structure also involves C–H· · ·π weak π-π stacking interaction [centroid–centroid separation = 3.806 (3) Å]. |
| Description: | Open Access |
| URI: | http://hdl.handle.net/2289/6413 |
| ISSN: | 1580-3155 |
| Alternative Location: | http://dx.doi.org/10.17344/acsi.2015.1436 |
| Copyright: | 2015 Slovenian Chemical Society |
| Appears in Collections: | Research Papers (SCM) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2015_Acta. Chim. Slov._62_768.pdf | Open Access | 346.08 kB | Adobe PDF | View/Open |
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