Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/6992
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dc.contributor.authorMohammad, AbdulKarim-Talaq-
dc.contributor.authorSrinivasa, H.T.-
dc.contributor.authorAl-Majidi, Suaad Mohammed Husain-
dc.contributor.authorAlajrawy, Othman Ibraheem-
dc.date.accessioned2018-09-04T15:06:43Z-
dc.date.available2018-09-04T15:06:43Z-
dc.date.issued2018-
dc.identifier.citationLiquid Crystals, 2018, Vol.45, p 1699-1710en_US
dc.identifier.issn0267-8292-
dc.identifier.issn1366-5855 (Online)-
dc.identifier.urihttp://hdl.handle.net/2289/6992-
dc.descriptionRestricted Access.en_US
dc.description.abstractThe four new homologous series of symmetric Isoflavon dimers were synthesised using varied alkyl/aryl diamines in linear sense. The chemical structures of the molecules were characterised by IR, NMR and CHNS analysis. Further, Liquid crystalline properties were verified using the combination of differential scanning calorimetry (DSC) and polarised optical microscope (POM). The molecular systems studied here reveal that LC property depends on the length of the middle connecting diamine spacer along with terminal alkyl spacer. The lower members favour to exhibit smectic A phase, whereas higher members exhibit nematic mesophase. The nature of LC property behaviours is supported by molecular geometries studied by DFT calculations.en_US
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.relation.urihttps://doi.org/10.1080/02678292.2018.1475685en_US
dc.rights2018 Taylor & Francisen_US
dc.subjectIsoflavon heterocycleen_US
dc.subjectcoumarinen_US
dc.subjectliquid crystalen_US
dc.subjectmesophaseen_US
dc.subjectdimersen_US
dc.titlePreparation, spectral and thermal properties of new Isoflavone derivatives: mesomorphic properties and DFT studiesen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (SCM)

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